Luminescent Metal–Organic Frameworks (MOFs) as a Chemopalette: Tuning the Thermochromic Behavior of Dual‐Emissive Phosphorescence by Adjusting the Supramolecular Microenvironments

Two classical copper(I)‐cluster‐based luminophores, namely, Cu₄I₄ and [Cu₃Pz₃]₂ (Pz=pyrazolate), are immobilized in a supramolecular system through the formation of metal–organic framework (MOF) materials. This series of luminescent MOF materials, namely, [Cu₄I₄(NH₃)Cu₃( L1 )₃]_n, [Cu₄I₄(NH₂CH₃)Cu₃( L1 )₃]_n, and [Cu₄I₄Cu₃( L2 )₃]_n ( L1 =3‐(4‐pyridyl)‐5‐(p‐tolyl)pyrazolate; L2 =3‐(4‐pyridyl)‐5‐(2,4‐dimethylphenyl)pyrazolate), exhibit diverse thermochromism attributed to the relative functioning efficacy of the two coordination luminophores. Such an intriguing chemopalette effect is regulated by the different supramolecular microenvironments between the two‐dimensional layers of these MOFs, and in particular, by the fine‐tuned Cu–Cu distances in the excimeric [Cu₃Pz₃]₂ luminophore. The structure–property elucidation of the thermochromic behavior allows one to understand these optical materials with unusual dual‐emissive properties.     

水介质中丁腈橡胶溶胀机理及其对磨粒磨损行为影响

研究首先对不同丙烯腈质量分数的丁腈橡胶（18%、26%和41%,即N18、N26和N41）进行浸泡试验分析基于溶胀时间的静态溶胀行为. 然后进一步对溶胀前后的丁腈橡胶样品进行圆型及角型磨粒单向滑动磨粒磨损试验. 为了揭示丁腈橡胶的溶胀机理及溶胀对不同粒型作用下磨粒磨损行为的影响,对试样进行质量、硬度、交联链比重（NMR）和表面形貌（SEM）测试. 结果表明:丁腈橡胶溶胀度随时间的增加而增加,并于240 h后趋于平衡,溶胀影响下老化的主要原因为交联链破坏和物质溶解.丁腈橡胶硬度随溶胀时间的增加而降低. 溶胀后摩擦系数和磨损量增加,同粒径下磨粒磨损程度角型大于圆型,角型磨损受溶胀影响程度更大,其最大溶胀后磨损增量为圆型磨粒的1.56倍. 圆型和角型磨粒分别以滚动和滑动的方式进入摩擦副,形成压入坑和嵌入坑两种不同的表面形貌,溶胀后橡胶组织疏松软化导致表面凹坑加深. 丁腈橡胶溶胀及其对磨粒磨损的影响程度随丙烯腈含量的增加而减小.      

随机变量和的模函数分布及其应用

介绍了一个在计算机科学、信息科学等学科中具有广泛应用的随机变量和的模函数,计算了其分布,并提供了该函数在图像信息安全领域的一个应用例子,验证了理论结果.     

Switchable erbium-doped fiber ring laser based on Sagnac loop mirror incorporating few-mode high birefringence fiber

Without the need of any other additional filtering device, a triple-wavelength switchable erbium-doped fiber ring laser based on Sagnac loop mirror incorporating a piece of few-mode high birefringence fiber is newly proposed and experimentally demonstrated. Three potential lasing wavelengths at about 2.0 nm interval with the side mode suppression ratio higher than 40 dB can be switched mainly by adjusting a polarization controller next to the few-mode high birefringence fiber in the Sagnac loop. In addition to the stable single-line lasing operation, simultaneous dual- and triple-line oscillations are also highly stable at room temperature with suppressing the intrinsic homogeneous gain broadening of the erbium-doped fiber.     

Hydroxyl Group Modifies Aggregation Behavior of a Non-ionic Hydro-fluorocarbon Hybrid Surfactant by Disrupting Interracial Water

Two non-ionic hydro-fluorocarbon hybrid surfactants with and without hydroxyl groups were synthesized and compared. They exhibited good thermal stability and superior surface activity. It was observed that the hydroxyl group had a profound effect on modifying the surface tension of their solutions and the morphology of the formed micelles. This effect may be attributed to the rearranging of the alkane group from above the air/aqueous surface to below it and the disrupting of the interfacial water structure induced by the hydroxyl groups. This work provides a strategy to weaken the immiscibility between hydrocarbon and fluorocarbon chains by modifying their orientational structure at the interface, thus it is helpful for the design of surfactants with varied interfacial properties.     

Geodesic vector fields and Eikonal equation on a Riemannian manifold

In this paper, we study the impact of geodesic vector fields (vector fields whose trajectories are geodesics) on the geometry of a Riemannian manifold. Since, Killing vector fields of constant lengths on a Riemannian manifold are geodesic vector fields, leads to the question of finding sufficient conditions for a geodesic vector field to be Killing. In this paper, we show that a lower bound on the Ricci curvature of the Riemannian manifold in the direction of geodesic vector field gives a sufficient condition for the geodesic vector field to be Killing. Also, we use a geodesic vector field on a 3-dimensional complete simply connected Riemannian manifold to find sufficient conditions to be isometric to a 3-sphere. We find a characterization of an Einstein manifold using a Killing vector field. Finally, it has been observed that a major source of geodesic vector fields is provided by solutions of Eikonal equations on a Riemannian manifold and we obtain a characterization of the Euclidean space using an Eikonal equation.     

疣荔枝螺微粒体细胞色素P450酶系的光谱分析

从疣荔枝螺内脏团制备得到微粒体,用UV mini-1240分光光度计对细胞色素P450酶系的三种主要成分:细胞色素P450、细胞色素b5,NADPH-细胞色素P450还原酶进行了测定,并对微粒体酶液进行SDS-PAGE电泳测试,证明了疣荔枝螺体内含有细胞色素P450酶系的三种酶.     

Block Primitive 2- (v, k, 1) Designs Admitting a Ree Simple Group

In this paper, we prove that if D is a 2- (v, k, 1) design withG  ≤  Aut(D) block primitive and soc (G)  =  ²G₂(q) then D is a Ree unital with parameters 2- (q³ +  1, q +  1, 1).